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http://hdl.handle.net/2289/8692Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Palakshamurthy, B S | - |
| dc.contributor.author | Kumar, H Anil | - |
| dc.contributor.author | Devarajegowda, H C | - |
| dc.contributor.author | Srinivasa, H T | - |
| dc.contributor.author | Kumar, M Harish | - |
| dc.date.accessioned | 2026-03-25T06:09:04Z | - |
| dc.date.available | 2026-03-25T06:09:04Z | - |
| dc.date.issued | 2025-05 | - |
| dc.identifier.citation | Acta Crystallographica E: Crystallographic Communications, 2025, Vol. 81 (5), p364-367 | en_US |
| dc.identifier.issn | 2056-9890 | - |
| dc.identifier.uri | http://hdl.handle.net/2289/8692 | - |
| dc.description | Open Access. | en_US |
| dc.description.abstract | In the title compound, C20H14BrClO3, the dihedral angles between the aromatic ring of the 4-bromo-2-chlorophenyl and the immediate neighbour and second aromatic ring of the biphenyl moiety are 80.59 (2) and 75.42 (2)°, respectively. The dihedral angle between the rings within the biphenyl moiety is 24.57 (4)°. The torsion angle associated with the ester group linking the biphenyl ring and the 4-bromo-2-chlorophenyl group is −166.6 (2)°. The extended structure features short halogen⋯oxygen contacts [Cl⋯O = 2.991 (3), Br⋯O = 3.139 (2) Å], forming molecular sheets lying parallel to (101). The Hirshfeld surface analysis reveals that the major contributions to the intermolecular interactions are from C⋯H/H⋯C (32.2%), H⋯H/H⋯H (26.3%), Br⋯H/H⋯Br (10.7%), O⋯H/H⋯O (10.4%) and Cl⋯H/H⋯Cl (7.5%) contacts. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Acta Crystallographica E: Crystallographic Communications | en_US |
| dc.relation.uri | https://doi.org/10.1107/S2056989025002658 | en_US |
| dc.rights | © The Authors 2025 | en_US |
| dc.subject | crystal structure | en_US |
| dc.subject | biphenyl | en_US |
| dc.subject | Hirshfeld surface | en_US |
| dc.title | Synthesis and structure of 4-bromo-2-chlorophenyl 4′-methoxy-[1,1′-biphenyl]-4-carboxylate featuring short halogen⋯oxygen contacts | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | Research Papers (SCM) | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2025_Acta Crystallographica E_Vol 81 (5)_p364-367.pdf Restricted Access | Open Access | 5.77 MB | Adobe PDF | View/Open Request a copy |
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