Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/7410
Title: Pseudopolar smectic-C phases of azo-substituted achiral bent-core hockey-stick-shaped molecules
Authors: Malkar, Deepshika
Monika, M.
Prasad, Veena
Roy, Arun
Issue Date: 2-Jan-2020
Publisher: American Physical Society
Citation: Physical Review E, 2020, Vol.101, p012701
Abstract: We report experimental studies on an azo-substituted compound consisting of bent-core hockey-stick-shaped molecules. The experimental results establish two pseudopolar tilted smectic phases, which are characterized by an in-plane axial-vector order parameter in addition to tilt order in the smectic layers. Electro-optical measurements in the mesophases indicate that the birefringence of the sample strongly depends on the applied electric field. We develop a theoretical model to account for this observation. The change in the birefringence of the sample arises from the field-induced reorientation of the tilt plane of the molecules in the layer above a threshold field. The effect is analogous to the field-induced Freedericksz transition which is quadratic in the applied electric field.
Description: Open Access
URI: http://hdl.handle.net/2289/7410
ISSN: 2470-0045
2470-0053 (Online)
Alternative Location: https://doi.org/10.1103/PhysRevE.101.012701
Copyright: 2020 American Physical Society
Appears in Collections:Research Papers (SCM)

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