Columnar self-assembly of novel benzylidenehydrazones and their difluoroboron complexes: structure–property correlations†

Vinayakumara, D.R.; Swamynathan, K.; Kumar, Sandeep; Adhikari, A.V.

Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/7222

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DC Field	Value	Language
dc.contributor.author	Vinayakumara, D.R.	-
dc.contributor.author	Swamynathan, K.	-
dc.contributor.author	Kumar, Sandeep	-
dc.contributor.author	Adhikari, A.V.	-
dc.date.accessioned	2019-06-06T18:15:38Z	-
dc.date.available	2019-06-06T18:15:38Z	-
dc.date.issued	2019-05-14	-
dc.identifier.citation	New Journal of Chemistry, 2019, Vol.43, p7099	en_US
dc.identifier.issn	1144-0546	-
dc.identifier.uri	http://hdl.handle.net/2289/7222	-
dc.description	Restricted Access.	en_US
dc.description.abstract	Organoboron complexes are considered to be an important class of optically dynamic materials and because of their imperative properties, they have been unceasingly studied in a wide range of scientific areas. In this context, a new family of D–A–D0 architectured boron difluoride complexes FB1–4 derived from arylhydrazones HZ1–4 has been synthesized and characterized. The work also deliberates detailed studies on their thermal, self-assembling and optoelectronic properties with respect to structural modifications. The systematic studies reveal that the new arylhydrazone ligands and their BF2 complexes exhibit a prospective columnar mesomorphism with different 2D lattice geometries at room temperature, owing to their critical structural features. Interestingly, an unusual morphological cross-over from a columnar hexagonal to rectangular mesophase has been confirmed in one of the investigated pseudo-discoidal boron complexes, FB4. The optoelectronic studies showcased their ICT dominating dye properties. Finally, the experimental results have been consciously correlated with quantum chemical simulations.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.relation.uri	https://doi.org/10.1039/C9NJ01192G	en_US
dc.rights	2019 The Royal Society of Chemistry and the Centre National dela Recherche Scientifique	en_US
dc.title	Columnar self-assembly of novel benzylidenehydrazones and their difluoroboron complexes: structure–property correlations†	en_US
dc.type	Article	en_US
Appears in Collections:	Research Papers (SCM)

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