Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/5868
Title: Effects of chain branching and lateral fluorine substitution on mesomorphism of cholesteryl benzoates
Authors: Varia, M.C.
Srinivasa, H.T.
Kumar, Sandeep
Keywords: chiral nematic N phase,
blue phase
TGBA phase
smectic A phase
Issue Date: Feb-2014
Publisher: Taylor & Francis
Citation: Liquid Crystals, 2014, Vol.41, p 883-890
Abstract: The mesogenic cholesteryl 4′-alkoxyphenyl-4-carboxylates possessing terminal normal/branched/saturated/unsaturated alkyl chains with laterally ortho/meta substituted electronegative fluorine atom are described. All the homologues exhibited enantiotropic mesomorphism. Smectic A phase, chiral nematic, blue phase (BP) and TGBA phases were observed in different homologues. All the novel compounds were characterised by spectroscopic and elemental analysis. Thermal investigations and mesophase characterisations for all the compounds were carried out by the combination of DSC, POM and X-ray analysis. The effects of the various terminal normal/branched/saturated/unsaturated alkyl chains and the position of the substituted fluorine atom with its structurally related compounds have been discussed.
Description: Restricted Access.
URI: http://hdl.handle.net/2289/5868
ISSN: 0267-8292
1366-5855 (Online)
Alternative Location: http://dx.doi.org/10.1080/02678292.2014.882422
Copyright: 2014 Taylor & Francis
Appears in Collections:Research Papers (SCM)

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