Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/5094
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dc.contributor.authorVaria, M.C.-
dc.contributor.authorKumar, Sandeep-
dc.contributor.authorPrajapati, A.K.-
dc.date.accessioned2012-07-27T09:50:30Z-
dc.date.available2012-07-27T09:50:30Z-
dc.date.issued2012-08-
dc.identifier.citationLiquid Crystals, 2012, Vol.39, p933-942en
dc.identifier.issn0267-8292-
dc.identifier.issn1366-5855 (online)-
dc.identifier.urihttp://hdl.handle.net/2289/5094-
dc.descriptionRestricted Access.en
dc.description.abstractNew unconventional T-shaped non-symmetrical dimeric liquid crystalline compounds have been synthesised and their thermotropic properties studied on the hot-stage of a polarising microscope. These compounds consist of an azo-ester mesogenic unit with a range of terminal substituents (–CH3, –OCH3, –NO2 or –Cl) at one end, interconnected by a flexible spacer (n = 4, 5 or 10) via ether and ester linking units to a biphenyl moiety at the lateral hydroxyl position of the azo-ester. All the compounds were characterised using a combination of elemental analysis and standard spectroscopic methods. The compounds were found to exhibit enantiotropic nematic and smectic mesophases. The effect of different terminal substituents on mesomorphism is discussed.en
dc.language.isoenen
dc.publisherTaylor & Francisen
dc.relation.urihttp://dx.doi.org/10.1080/02678292.2012.687780en
dc.rights2012 Taylor & Francisen
dc.subjectazo-esteren
dc.subjectether–ester linkageen
dc.subjectflexible spacersen
dc.subjectT-shapeden
dc.subjectnon-symmetrical dimers,en
dc.subjectsmectic Aen
dc.titleT-shaped non-symmetrical twin liquid crystalline compoundsen
dc.typeArticleen
Appears in Collections:Research Papers (SCM)

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