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Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/4727
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dc.contributor.authorMathur, P.-
dc.contributor.authorGhose, Sanjukta-
dc.contributor.authorTrivedi, Rajiv-
dc.contributor.authorGelinsky, Michael-
dc.contributor.authorRombach, Michael-
dc.contributor.authorPhilip, Reji-
dc.date.accessioned2012-06-19T03:46:49Z-
dc.date.available2012-06-19T03:46:49Z-
dc.date.issued2000-
dc.identifier.citationJournal of Organometallic Chemistry, 2000, Vol.595, p140en
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/2289/4727-
dc.descriptionRestricted Access. An open-access version is available at arXiv.org (one of the alternative locations)en
dc.description.abstractA novel dimolybdenum complex in which the metal atoms are bridged by two different chalcogens and two thiolato ligands has been synthesised and structurally characterised. This complex shows a large third-order optical nonlinearity as measured by degenerate four-wave mixing with picosecond excitation at 532 nm. A hyperpolarisability (γ) of 1.2×10−30 esu has been obtained. The structure of the complex was established by the single-crystal X-ray diffraction method. It consists of a Mo–Mo unit, which is bridged by one S, one Te and two (SPh) groups. Each Mo atom also has a (η5-C5H5) group attached to it.en
dc.language.isoenen
dc.publisherElsevier B. V.en
dc.relation.urihttp://arxiv.org/abs/en
dc.relation.urihttp://dx.doi.org/10.1016/S0022-328X(99)00648-8,en
dc.rights2000 Elsevier B. V.en
dc.titleSynthesis, optical nonlinearity and crystal structure of a novel mixed-chalcogen, thiolato-bridged complex [(5-C5H5)2Mo2(µ-S)(µ-Te)(µ-SPh)2en
dc.typeArticleen
Appears in Collections:Research Papers (LAMP)

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