1. RRI Digital Repository
  2. 05. Light and Matter Physics
  3. Research Papers (LAMP)
Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/4726
Full metadata record
DC FieldValueLanguage
dc.contributor.authorPhilip, Reji-
dc.contributor.authorKumar, G.R.-
dc.contributor.authorMathur, P.-
dc.contributor.authorGhose, S.-
dc.date.accessioned2012-06-19T03:46:14Z-
dc.date.available2012-06-19T03:46:14Z-
dc.date.issued2000-05-
dc.identifier.citationOptics Communications, 2000, Vol.178, p469-475.en
dc.identifier.issn0030-4018-
dc.identifier.urihttp://hdl.handle.net/2289/4726-
dc.descriptionRestricted Access. An open-access version is available at arXiv.org (one of the alternative locations)en
dc.description.abstractStudies of the third order optical nonlinearity of the mixed-metal, mixed chalcogen clusters Cp2Mo2Fe2STe(CO)7 and Cp2Mo2Fe2(μ3-S)(μ3-Te)(μ2- SPh)(μ3-H)(CO)5 using 532 nm, 6 ns laser pulses are reported. The second compound is the first example in literature of a mixed Fe/Mo mixed chalcogen complex containing a bridging thiolate group. The effective nonlinear absorption coefficient and nonlinear index intensity coefficient of these compounds are measured by the Z-scan technique, from which the corresponding cubic hyperpolarizabilities are evaluated. The obtained values indicate a high nonlinearity comparable to some of the best values reported previously for cluster compounds. Both compounds show strong optical limiting. In addition, their photostability is found to be much superior to many of the previously reported highly nonlinear clusters.en
dc.language.isoenen
dc.publisherElsevieren
dc.relation.urihttp://dx.doi.org/10.1016/S0030-4018(00)00673-8en
dc.relation.urihttp://adsabs.harvard.edu/abs/2000OptCo.178..469Pen
dc.rights2000 Elsevieren
dc.titleNonlinear optical properties of mixed Mo/Fe, mixed chalcogen clusters Cp2Mo2Fe2STe(CO)7and Cp2Mo2Fe2(m3-S)(m3-Te)(m2-SPh)(m3-H)(CO)5en
dc.typeArticleen
Appears in Collections:Research Papers (LAMP)

Files in This Item:
File Description SizeFormat 
2000_Optics Communications_V178_p469.pdf
  Restricted Access		Restricted Access123.6 kBAdobe PDFView/Open Request a copy
Show simple item record


Items in RRI Digital Repository are protected by copyright, with all rights reserved, unless otherwise indicated.