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|Title: ||Synthesis, characterization and third-order nonlinear optical studies of copper complexes containing 1,10-phenanthroline-5,6-dione and triphenylphosphine ligands|
|Authors: ||Rudresha, B.J.|
Bhat, Ramachandra B.
Sampath Kumar, H.C.
Shiva Kumar, K.I.
|Keywords: ||Copper complexes|
Degenerate four wave mixing
|Issue Date: ||Mar-2011 |
|Publisher: ||Elsevier B.V.|
|Citation: ||Synthetic Metals, 2011, Vol.161, p535|
|Abstract: ||This research article describes the synthesis, characterization and third-order nonlinear optical studies of copper(I) complexes [Cu(Br)(N,N'-C(12)H(6)N(2)O(2))(PPh(3))] and [Cu(I)(N,N'-C(12)H(6)N(2)O(2))(PPh(3))] abbreviated as [CuBrLPPh(3)] (1) and [CulLPPh(3)] (2) (L= 1,10-phenanthroline-5,6-dione). Nonlinear optical properties of the complexes are investigated at 532 nm using single beam Z-scan and degenerate four-wave mixing (DFWM) techniques employing nanosecond laser pulses. The complexes show optical limiting behaviour due to "effective" two-photon absorption. The values of the effective two-photon absorption (2PA) coefficients (beta), third-order nonlinear susceptibilities (chi((3))), and figures of merit (F), are calculated|
|Description: ||Restricted Access.|
|Alternative Location: ||http://dx.doi.org/10.1016/j.synthmet.2010.12.006|
|Copyright: ||2010 Elsevier B.V.|
|Appears in Collections:||Research Papers (LAMP)|
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