Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/4022
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dc.contributor.authorPandey, Rakesh K.-
dc.contributor.authorLakshminarayanan, V.-
dc.date.accessioned2011-04-08T07:47:50Z-
dc.date.available2011-04-08T07:47:50Z-
dc.date.issued2010-05-13-
dc.identifier.citationJournal of physical chemistry C , 2010, Vol. 114, p8507en
dc.identifier.issn1932-7455 (Online)-
dc.identifier.issn1932-7447-
dc.identifier.urihttp://hdl.handle.net/2289/4022-
dc.descriptionRestricted Access.en
dc.description.abstractWe report in this study that a thin film of Pd nanoparticles dispersed in 3,4-polyethylenedioxythiophene (PEDOT) shows remarkable electrocatalytic activity toward hydrogen evolution reaction in acid medium and ethanol electro-oxidation reaction in alkaline medium. The method of preparation of Pd−PEDOT nanocomposite film involves the formation of Pd nanoparticles by the dissolution of Pd anode and simultaneous oxidative polymerization of 3,4-ethylenedioxythiophene followed by deposition as a thin film on the gold substrate. The highly enhanced catalytic activity of the nanocomposite film with a relatively low Pd concentration is attributed to the higher catalytic activity of nanosized Pd on gold substrate and the electrically conducting path provided by the PEDOT matrix.en
dc.language.isoenen
dc.publisherAmerican Chemical Societyen
dc.relation.urihttp://dx.doi.org/10.1021/jp1014687en
dc.rights2010 American Chemical Societyen
dc.titleEnhanced electrocatalytic activity of pd-dispersed 3,4-polyethylenedioxythiophene film in hydrogen evolution and ethanol electro-oxidation reactionsen
dc.typeArticleen
Appears in Collections:Research Papers (SCM)

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