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Title: | Static and dynamic light scattering on aligned solution of root like polymer |
Authors: | Desvignes, N. Suresh, K.A. Berry, G.C. |
Issue Date: | 1993 |
Publisher: | John Wiley |
Citation: | Journal of Applied Polymer Science, 1993, Vol.52, p33-43 |
Abstract: | Static and dynamic light scattering are described on well-aligned nematic solutions of the rodlike poly(1.4-phenylene-2.6-benzobisthiazole) (PBT). The data are used to discuss the Frank elastic constants Kμ for curvature distortions and the corresponding distortion viscosities ημ (μ = S for splay, T for twist, and B for bend). Data were obtained on a PBT at three concentrations over the range 1.1 < Ψ/ΨNI < 2 where Ψ is the polymer volume fraction and ΨNI the value of Ψ required to form the nematic phase. The data show that ηB/KB < ηT/KT, as expected, but do not give the pronounced dependence of on ηB/KB on Ψ predicted for rodlike chains. Possible explanations for the observed behavior are discussed. |
Description: | Restricted Access. |
URI: | http://hdl.handle.net/2289/3230 |
ISSN: | 0021-8995 1097-4628 (Online) |
Copyright: | 1993 1993 John Wiley & Sons |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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1993 JAPS-Applied Polymer Symposium V52 p33.pdf Restricted Access | Restricted Access. | 463.4 kB | Adobe PDF | View/Open Request a copy |
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