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http://hdl.handle.net/2289/3169
Title: | Ferroelectric properties exhibited by mesophases of compounds composed of achiral banana-shaped molecules |
Authors: | Reddy, Amaranatha R. Sadashiva, B.K. |
Issue Date: | 2002 |
Publisher: | Royal Society of Chemistry |
Citation: | Journal of Materirals Chemistry, 2002, Vol.12, p2627-2632 |
Abstract: | The synthesis and mesomorphic properties of a new series of five-ring esters composed of banana-shaped molecules are reported. The homologues containing n-dodecyloxy, n-tetradecyloxy and n-hexadecyloxy terminal chains exhibit a smectic phase while that with an n-octadecyloxy chain shows a two-dimensional structure. The structures of the mesophases have been determined by X-ray diffraction studies. Interestingly both these mesophases exhibit ferroelectric properties. The electro-optical switching characteristics have been investigated using both triangular-wave and d.c. electric fields. Ferroelectricity is clearly demonstrated in both the mesophases by bistable switching behaviour. |
Description: | Restricted Access. |
URI: | http://hdl.handle.net/2289/3169 |
ISSN: | 0959-9428 1364-5501 (Online) |
Alternative Location: | http://dx.doi.org/10.1039/b204474a |
Copyright: | 2002 Royal Society of Chemistry |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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2002 JOURNAL OF MATERIALS CHEM V12 2627p.pdf Restricted Access | Restricted Access | 327.06 kB | Adobe PDF | View/Open Request a copy |
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