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Title: Differential exchange and molecular structure of 2,6-dichlorophenol as studied by NMR in nematic solvents
Authors: Lakshminarayana, M.R.
Kunwar, A.C.
Khetrapal, C.L.
Issue Date: Nov-1984
Publisher: Elsevier B.V.
Citation: Journal of Magnetic Resonance, 1984, Vol.60, p184-189
Abstract: The proton NMR spectra of 2,6-dichlorophenol without 13C---H satellites are of the AB2 and AB2C types in N-(p′-ethoxybenzylidene)-p-n-butylaniline (EBBA) and in a ternary mixture of propyl, pentyl, and heptyl bicyclohexyl carbonitrile (ZLI-1167), respectively. The vibrationally corrected structure of the molecule is derived from the spectra including 13C---H satellites. The importance of the studies in a mixture of two solvents of opposite diamagnetic anisotropies at the critical point where two spectra of 2,6-dichlorophenol coexist, is pointed out.
Description: Restricted Access.
ISSN: 0022-2364
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Copyright: 1984 Elsevier B.V.
Appears in Collections:Research Papers (SCM)

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