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http://hdl.handle.net/2289/3167| Title: | Differential exchange and molecular structure of 2,6-dichlorophenol as studied by NMR in nematic solvents |
| Authors: | Lakshminarayana, M.R. Kunwar, A.C. Khetrapal, C.L. |
| Issue Date: | Nov-1984 |
| Publisher: | Elsevier B.V. |
| Citation: | Journal of Magnetic Resonance, 1984, Vol.60, p184-189 |
| Abstract: | The proton NMR spectra of 2,6-dichlorophenol without 13C---H satellites are of the AB2 and AB2C types in N-(p′-ethoxybenzylidene)-p-n-butylaniline (EBBA) and in a ternary mixture of propyl, pentyl, and heptyl bicyclohexyl carbonitrile (ZLI-1167), respectively. The vibrationally corrected structure of the molecule is derived from the spectra including 13C---H satellites. The importance of the studies in a mixture of two solvents of opposite diamagnetic anisotropies at the critical point where two spectra of 2,6-dichlorophenol coexist, is pointed out. |
| Description: | Restricted Access. |
| URI: | http://hdl.handle.net/2289/3167 |
| ISSN: | 0022-2364 |
| Alternative Location: | http://dx.doi.org/10.1016/0022-2364(84)90324-X |
| Copyright: | 1984 Elsevier B.V. |
| Appears in Collections: | Research Papers (SCM) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 1984 JMR V60 p184.pdf Restricted Access | Restricted Access | 359.97 kB | Adobe PDF | View/Open Request a copy |
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