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DC Field | Value | Language |
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dc.contributor.author | Chandrasekhar, S. | - |
dc.contributor.author | Savithramma, K.L. | - |
dc.contributor.author | Madhusudana, N.V. | - |
dc.date.accessioned | 2007-06-25T09:03:39Z | - |
dc.date.available | 2007-06-25T09:03:39Z | - |
dc.date.issued | 1984 | - |
dc.identifier.citation | Proceedings of the 4th international symposium on liquid crystals & ordered fluids, Las Vegas, 1982, Eds. A C Griffin & J F Johnson, Plenum, 1984, p299-309 | en |
dc.identifier.uri | http://hdl.handle.net/2289/3118 | - |
dc.description | Restricted Access. | en |
dc.description.abstract | McMillan’s mean field model of smectic A is extended so that the translational order parameter is now periodic in two dimensions. The theory is developed for a face-centered rectangular lattice composed of liquid-like columns, taking the molecular cores to be circular discs normal to the columnar axes but with an asymmetrical disposition of the chains. When the axial ratio b/a =square root 3, the rectangular lattice reduces to a hexagonal one and the theory becomes essentially identical to that. proposed very recently by Feldkamp , Handschy and Clark. When b/a = square root 3 or departs from it only slightly, it turns out that the transition from the columnar to the isotropic phase may take place either directly or via a nematic phase, depending on the model potential parameters (a). Interpreting a to be a measure of the chain lengths as in McMillanls theory, the phase diagram is in broad agreement with the trends exhibited by the hexa-n-alkoxybenzoates of triphenylene. For higher values of b/a the theory predicts a columnar-smectic A transition as well. The new smectic A phase is biaxial. The possibility of such a phase occurring in real systems is discussed briefly | en |
dc.format.extent | 334405 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | en | en |
dc.publisher | Plenum | en |
dc.rights | 1984 Plenum | en |
dc.title | Extension of McMillan's model to liquid crystals of disc-like molecules | en |
dc.type | Article | en |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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1984 Proc 4th Int sym on LC & ordered fluids p299.pdf Restricted Access | Restricted Access | 326.57 kB | Adobe PDF | View/Open Request a copy |
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