Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/3048
Title: The re-entrant nematic phase in some pure compounds and their mixtures at atmospheric pressure
Authors: Moodithaya, K.P.L.
Madhusudana, N.V.
Issue Date: 1980
Publisher: Heyden
Citation: Proceedings of the international liquid crystals conference, Bangalore, 1979. Ed. S Chandrasekhar. Heyden, 1980, p121-129
Abstract: Recently we reported the occurrence of the re-entrant nematic phase in three pure compounds at atmospheric pressure: (i) trans-p-n-decyloxy-a-methyl-p'- cyanophenyl cinnamate (10 OMCPC), (ii) 4-cyanophenyl-3-methyl-4(4-n-undecyl- benzoyloxy) benzoate (11CPMBB) and (iii) 4-cyanophenyi-3-methyl-4 (4-n-dodecyl- benzoy loxy) benzoate (12CPMBB) . We have now studied the light scattering arising from twist fluctuations as a function of temperature in these compounds which again confirms the formation of the re-entrant nematic phase. We also present in this paper, phase diagrams of binary mixtures involving these compounds. In addition, we have determined the orientational order parameter in the nematic, smectic A and re-entrant nematic phases using (a) infrared dichroic studies on homeotropically aligned samples, and (b) optical birefringence studies again on homeotropically aligned samples employing a new technique.
Description: Restricted Access.
URI: http://hdl.handle.net/2289/3048
ISBN: 0-85501-163-7
Copyright: 1980 Heyden
Appears in Collections:Research Papers (SCM)

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