Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2731
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dc.contributor.authorSuryaprakash, N.-
dc.contributor.authorKunwar, A.C.-
dc.contributor.authorKhetrapal, C.L.-
dc.date.accessioned2007-06-11T09:52:53Z-
dc.date.available2007-06-11T09:52:53Z-
dc.date.issued1984-
dc.identifier.citationChemical Physics Letters, 1984, Vol.107, p333-336en
dc.identifier.issn0009-2614-
dc.identifier.urihttp://hdl.handle.net/2289/2731-
dc.descriptionRestricted Access.en
dc.description.abstractThe proton NMR spectra of N-methylpyrrole oriented in the nematic phases of liquid crystals with positive and negative diamagnetic anisotropies and their mixtures are reported. Geometrical parameters derived from the spectra at the critical point in the mixture of liquid crystals with positive and negative diamagnetic anisotropies, where macroscopic diamagnetic anisotropy vanishes, are similar to those obtained in the solvent with negative diamagnetic anisotropy. However, significant distortions in the molecular structure attributed to solvent effects have been observed in liquid crystals with positive diamagnetic anisotropy. The minimum energy conformation has one C---H of the methyl perpendicular to the ring.en
dc.format.extent199400 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.publisherElsevier B.V.en
dc.relation.uridoi:10.1016/0009-2614(84)85139-8en
dc.rights1984 Elsevier B.V.en
dc.titleSolvent effects on the structure of N-methylpyrrole as studied by NMR in nematic solventsen
dc.typeArticleen
Appears in Collections:Research Papers (SCM)

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