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Title: | A new kind of A-A transition: Studies on binary mixtures of terminally substituted cyano and nitro compounds |
Authors: | Shashidhar, R. Ratna, B.R. Krishna Prasad, S. |
Issue Date: | Jun-1984 |
Publisher: | Gordon and Breach Science Publishers. |
Citation: | Molecular Crystals and Liquid Crystals, 1984, Vol.102, p105 -111 |
Abstract: | High pressure, Xray and miscibility studies on binary mixtures of terminally substituted cyano and nitro compounds have led to the observation of two kinds of A-A transitions, viz., Ad-Ad and Ad-A1, the former being observed for the first time. The signatures of these transitions, which are not observable either optically or by differential scanning calorimetry, are seen dramatically in the smectic A -nematic phase boundary in the P-T plane. Xray results show that the Ad-Ad transition is from a partially bilayer smectic A with a temperature-independent layer spacing to one with a temperature-dependent layer spacing. |
Description: | Restricted Access. |
URI: | http://hdl.handle.net/2289/2490 |
ISSN: | 1058-725X |
Alternative Location: | http://dx.doi.org/10.1080/01406568408070519 |
Copyright: | 1984 OPA (Overseas Publishers Association) N.V. |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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1984 MCLC Lett V102 p105.pdf Restricted Access | Restricted Access | 203.82 kB | Adobe PDF | View/Open Request a copy |
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