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Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2348

Title: Mesomorphic properties of a homologous series of aryl beta-diketones and a few related derivatives
Authors: Sadashiva, B.K.
Rani Rao, P.
Srikanta, B.S.
Keywords: b.beta-diketone
smectic A phase
isomerism
substituent effect
Issue Date: Mar-1989
Publisher: Gordon and Breach Science Publishers.
Citation: Molecular Crystals and Liquid Crystals, 1989, Vol.168, p103-109
Abstract: A new homologous series of nine [l-(p-n-alkylbiphenyl)3-(phenyl)propane]1,3-diones have been prepared and their mesomorphic properties studied. The first four homologues in the series exhibit the classical nematic phase and a smectic phase, the next five showing only a smectic phase. The optical textures, miscibility and the X-ray data establish that the smectic phase is of the A1 type. This is perhaps the first instance of a b.beta-diketone exhibiting a nematic as well as a smectic A1 phase. In addition, a few similar isomeric b.beta-diketones have also been synthesized to study the terminal substituent effect on the mesomorphic properties.
Description: Restricted Access.
URI: http://hdl.handle.net/2289/2348
ISSN: 1058-725X
Alternative Location: http://dx.doi.org/10.1080/00268948908045963
Copyright: 1989 OPA (Overseas Publishers Association) N.V.
Appears in Collections:Research Papers (SCM)

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