Crystal and molecular structure of the discogen bis[1,3-di(p-n-octyloxy-phenyl)propane-1,3-dionato]copper(II)

Usha, K.; Vijayan, Kalyani

Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2345

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DC Field	Value	Language
dc.contributor.author	Usha, K.	-
dc.contributor.author	Vijayan, Kalyani	-
dc.date.accessioned	2007-05-19T09:28:19Z	-
dc.date.available	2007-05-19T09:28:19Z	-
dc.date.issued	1989-09	-
dc.identifier.citation	Molecular Crystals and Liquid Crystals, 1989, Vol.174 , p39-48	en
dc.identifier.issn	1058-725X	-
dc.identifier.uri	http://hdl.handle.net/2289/2345	-
dc.description	Restricted Access.	en
dc.description.abstract	The transition metal containing discogenic bis[1,3-di(p-n-octyloxy phenyl)propane-1,3-di-onato]copper(II) crystallizes in the triclinic space group P1 with two molecules in a unit cell of dimensions a = 11.300(9), b = 16.101(1), c = 17.089(2)Å, agr = 82.23(1), b.beta = 74.88(4), b.gamma = 77.43(3)°. The crystal structure was solved by direct methods and refined to R = 0.097 by the structure factor least squares procedure. The copper atom is surrounded by four oxygen atoms in a square planar arrangement. The octyloxy chains are fully extended. The crystal structure has both layer-like and columnar characteristics. The repeating unit along the column is a molecular pair. The copper atoms are distributed about the column axis in a zig-zag fashion.	en
dc.format.extent	475326 bytes	-
dc.format.mimetype	application/pdf	-
dc.language.iso	en	en
dc.publisher	Gordon and Breach Science Publishers.	en
dc.relation.uri	http://dx.doi.org/10.1080/00268948908042693	en
dc.rights	1989 OPA (Overseas Publishers Association) N.V.	en
dc.subject	discotic	en
dc.subject	copper complex	en
dc.subject	crystal structure	en
dc.title	Crystal and molecular structure of the discogen bis[1,3-di(p-n-octyloxy-phenyl)propane-1,3-dionato]copper(II)	en
dc.type	Article	en
Appears in Collections:	Research Papers (SCM)

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