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Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2337

Title: Crystal and molecular structure of the discogen bis[1,3-di(p-n-decylphenyl)propane-1,3-dionato]palladium(II)
Authors: Usha, K.
Vijayan, Kalyani
Sadashiva, B.K.
Rao, P.R.
Issue Date: Aug-1990
Publisher: Gordon and Breach Science Publishers.
Citation: Molecular Crystals and Liquid Crystals, 1990, Vol.185 , p1-11
Abstract: The transition metal containing discogen, bis[1,3-di(p-n-decylphenyl)propane-1,3-dionato]palladium(II) crystallizes in the triclinic space group P1 with one molecule in a unit cell of dimensions a = 10.260(2), b = 12.961(2), c = 13.403(2)Å, agr = 110.54(1), b.beta = 101.75(1) and b.gamma = 98.44(1)°. The crystal structure was solved by direct methods and refined using full matrix least squares procedure. The palladium atom is lying on an inversion center. The decyl chains are fully extended in an all trans conformation. In the crystal structure, the molecules form a tilted columnar arrangement. The angle between the normal to the core and the column axis is 68°. Each column is surrounded by six others. Along the column axis, adjacent palladium atoms are separated by 10.26Å.
Description: Restricted Access.
URI: http://hdl.handle.net/2289/2337
ISSN: 1058-725X
Alternative Location: http://dx.doi.org/10.1080/00268949008038485
Copyright: 1990 OPA (Overseas Publishers Association) N.V.
Appears in Collections:Research Papers (SCM)

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