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Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2332

Title: Synthesis and mesogenic properties of some beta-diketones and their copper (II) and palladium (II) chelates
Authors: Sadashiva, B.K.
Ghode, Archana
Rani Rao, P.
Keywords: b.beta-diketone
ligand
chelate
smectic
Issue Date: May-1991
Publisher: Gordon and Breach Science Publishers.
Citation: Molecular Crystals and Liquid Crystals, 1991, Vol.200, p187-196
Abstract: The paper deals with the synthesis and mesomorphic properties of some new copper (II) and palladium (II) complexes. Some of the ligands which are used to form these complexes also exhibit mesophases. The different mesophase types have been characterised. While none of the ligands shows a nematic phase, some of the copper and palladium chelates do exhibit a metastable nematic phase. A homologous series of eight bis[1-(p-n-alkylbiphenyl)3-(phenyl) propane 1,3-dionato copper (II) has been prepared and all the homologues show a metastable nematic phase. A plot of the nematic rarr isotropic transition temperatures versus the number of carbon atoms in the alkyl chain shows smooth curve relationship.
Description: Restricted Access.
URI: http://hdl.handle.net/2289/2332
ISSN: 1058-725X
Alternative Location: http://dx.doi.org/10.1080/00268949108044240
Copyright: 1991 OPA (Overseas Publishers Association) N.V.
Appears in Collections:Research Papers (SCM)

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