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Title: Crystal and molecular structure of the discogen bis[1,3-di(p-n-octylphenyl)propane-1,3-dionato]copper(II)
Authors: Usha, K.
Vijayan, Kalyani
Sadashiva, B.K.
Keywords: Discotic
copper complex
crystal structure
Issue Date: Jun-1991
Publisher: Gordon and Breach Science Publishers.
Citation: Molecular Crystals and Liquid Crystals, 1991, Vol.201, p13-21
Abstract: The transition metal containing discogen bis[1,3-di(p-n-octylphenyl)propane-1,3-dionato]copper(II) crystallizes in the triclinic space group P1. The copper atom lies on an inversion centre and is surrounded by four oxygen atoms in a square planar arrangement. The octyl chains are fully extended in an alltrans conformation. The molecules form a tilted columnar arrangement, the angle of tilt between the disc normal and the column axis being 122°. The column axis coincides with the crystallographic a-axis. In the crystal structure, each column is surrounded by six others. Along the column axis, adjacent copper atoms are separated by 5.821 (3) Å.
Description: Restricted Access.
ISSN: 1058-725X
Alternative Location:
Copyright: 1991 OPA (Overseas Publishers Association) N.V.
Appears in Collections:Research Papers (SCM)

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