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Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/2315

Title: A convenient and economic method for the synthesis of monohydroxy-pentaalkoxy- and hexaalkoxytriphenylene discotics
Authors: Kumar, Sandeep
Lakshmi, B.
Keywords: Triphenylene
Discotic liquid crystals
Monohydroxy-pentaalkoxytriphenylene
Oxidative trimerization
Iron(III) chloride
Issue Date: 11-Apr-2005
Publisher: Elsevier B.V.
Citation: Tetrahedron Letters,2005, Vol.46, p2603-2605
Abstract: A one-step process for the preparation of mono-functionalized triphenylene discotics is presented. Oxidative trimerization of ortho-dialkoxybenzenes using FeCl3 in nitromethane and a catalytic amount of various acids, furnished monohydroxy-pentaalkoxytriphenylene in addition to hexaalkoxytriphenylene. These products can be easily separated by column chromatography over aluminium oxide.
Description: Restricted Access.
URI: http://hdl.handle.net/2289/2315
ISSN: 0040-4039
Alternative Location: http://dx.doi.org/10.1016/j.tetlet.2005.02.099
Copyright: 2005 Elsevier B.V.
Appears in Collections:Research Papers (SCM)

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