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http://hdl.handle.net/2289/1079
Title: | Pressure studies on two discotic liquid crystals. |
Authors: | Raja, V.N. Shashidhar, R. Chandrasekhar, S. Boehm, R.E. Martire, D.E. |
Keywords: | Discotic Liquid crystals Columnar mesophase Pressure studies Phase diagrams |
Issue Date: | Jul-1985 |
Publisher: | Indian Academy of Sciences, Bangalore, India. |
Citation: | Pramana, 1985, Vol. 25, pL119-L-122. |
Abstract: | Pressure-temperature diagrams have becn studied for two discotic compounds, hexa-n-octyloxy triphenylene and hexa-n-decanoyloxytriphenylenc, both of which exhibit the columnar (D) phase at atmospheric pressure. Two interesting results, common to both compbunds, have been obtained: (a) in contrast to what is usually observed in liquid crystals of rod-like molecules, the columnar-isotropic (D-I) transition, which is enantiotropic at atmospheric pressure, becomes monotropic at high pressures; (b) dT/dP = 0 for the D-I transition, implying that despite the drastic change in the molecular order at this transition, the associated volume change is extremely small. |
URI: | http://hdl.handle.net/2289/1079 |
ISSN: | 0304-4289 |
Copyright: | Indian Academy of Sciences, Bangalore, India. |
Appears in Collections: | Research Papers (SCM) |
Files in This Item:
File | Description | Size | Format | |
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1985 Pramana V25 pL119.pdf | 4p. | 115.77 kB | Adobe PDF | View/Open |
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