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Enhanced smectic A mesophase in mixtures of two terminally polar compounds

dc.contributor.authorRaghunathan, V.A.
dc.contributor.authorUrs, Subramanya Raj M.
dc.contributor.authorMadhusudana, N.V.
dc.date.accessioned2007-05-23T06:45:16Z
dc.date.available2007-05-23T06:45:16Z
dc.date.issued1985
dc.descriptionRestricted Access.en
dc.description.abstractAn enhanced smectic A phase has been observed in mixtures of two terminally polar compounds, viz, 5-(4-n butylphenyl)-2-(4-cyanophenyl)-pyrimidine (4 PCPP) and n-dodecyl-4-(4'-nitrobenzoyloxy) benzoate (12 NBOB). The former is a nematogen and the latter non-mesomorphic with a hidden smectic A-isotropic transition. The smectic A-nematic transition boundary shows a parabolic shape, but with an unusually large tilt angle between the axis of the parabola and the composition axis. Mixtures in some composition range exhibit the reentrant nematic phase. Xray diffraction studies indicate that the smectic phase is of the Ad type. Low frequency dielectric constants and dispersion measurements of b.epsiVerbar; are also reported.en
dc.format.extent385600 bytes
dc.format.mimetypeapplication/pdf
dc.identifier.citationMolecular Crystals and Liquid Crystals, 1985, Vol.131, p9-19en
dc.identifier.issn1058-725X
dc.identifier.urihttp://hdl.handle.net/2289/2364
dc.language.isoenen
dc.publisherGordon and Breach Science Publishers.en
dc.relation.urihttp://dx.doi.org/10.1080/00268948508084190en
dc.rights1985 OPA (Overseas Publishers Association) N.V.en
dc.titleEnhanced smectic A mesophase in mixtures of two terminally polar compoundsen
dc.typeArticleen

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