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Phase transitions in colloidal dispersions in a liquid crystalline medium

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American Chemical Society

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We present experimental studies on colloidal suspensions in a lyotropic system exhibiting an isotropic-nematic-lamellar phase sequence upon decreasing the temperature. The particles are found to undergo a gas-liquid transition in the nematic phase of the suspending medium, indicating the existence of an attractive interparticle interaction. The resulting liquid phase is weakly anisotropic. Further, the nematic-lamellar transition of the liquid crystal is found to be accompanied by a liquid-solid transition of the particles.

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Langmuir, 2000, Vol.16, p4720-4725.

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2000 American Chemical Society