Synthesis and structure of 4-[(2,3,4,5,6-penta­fluoro­phen­­oxy)carbon­yl]phenyl 4-(dec­yl­oxy)benzoate

Abstract

In the title compound, C30H29F5O5, the dihedral angle between the central carbonyl­phenyl and peripheral perfluoro­phen­oxy and benzoate rings are 76.57 (2) and 69.71 (3)°, respectively. The pendant C10 alkyl chain adopts an all-anti conformation. In the crystal, weak C—H⋯O hydrogen bonds connect the mol­ecules, generating [010] C(7) chains. The packing is consolidated by C—H⋯F and C—H⋯π inter­actions and weak aromatic π–π stacking. A Hirshfeld surface analysis revealed that the major contributions to the packing are from H⋯H (42.2%), H⋯F/F⋯H (19.0%), H⋯O/O⋯H (10.3%), C⋯H/H⋯C (8.7%) and F⋯C/C⋯F (8.0%) contacts.