Some unusual properties of 4-n-decylphenyl-3'-methyl-4'-(4''-nitrobenzoyloxy)benzoate
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Gordon and Breach Science Publishers.
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4-n-Decylphenyl-3'-methyl-4'-(4''-nitro-benzoyloxy)benzoate (10 PMNBB) which exhibits the smectic A and nematic mesophases shows a large expansion (sim20%) of the bilayer spacing as it is cooled in the mesomorphic range. This is accompanied by a reversal in the sign of the dielectric anisotropy which becomes negative at lower temperatures.
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Molecular Crystals and Liquid Crystals Letters, 1982, Vol.82, p25-31
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1982 OPA (Overseas Publishers Association) N.V.