Optical limiting characteristics of Dichloridobis(1-ethyl-2, 6-dimethylpyridinium-4-olate-κO) zinc (II)
| dc.contributor.author | Philominal, A. | |
| dc.contributor.author | Dhanuskodi, S. | |
| dc.contributor.author | Philip, Reji | |
| dc.date.accessioned | 2012-06-21T06:56:39Z | |
| dc.date.available | 2012-06-21T06:56:39Z | |
| dc.date.issued | 2012-03 | |
| dc.description | Restricted Access. | en |
| dc.description.abstract | A newly synthesized metal-organic co-ordination compound Dichloridobis (1-ethyl-2,6- dimethylpyridinium-4-olate-kO) zinc(II) (EDMPZC) is characterized by FTIR to confirm the molecular structure. It crystallizes in the monoclinic system with the centrosymmetric space group C2/c and the unit cell parameters are determined from the single crystal X-ray diffraction analysis. Optical energy band gap is found to be 3.5 eV by UVeVisible absorption studies. The third order nonlinear optical properties were investigated by open-aperture Z-scan measurements using Nd:YAG laser (532 nm, 5 ns). Two-photon absorption and reverse saturable absorption mechanisms at the excitation wavelength are found to cause the observed optical limiting behavior. | en |
| dc.identifier.citation | Current Applied Physics, 2012, Vol.12, p401 | en |
| dc.identifier.issn | 1567-1739 | |
| dc.identifier.uri | http://hdl.handle.net/2289/4753 | |
| dc.language.iso | en | en |
| dc.publisher | Elsevier B. V. | en |
| dc.relation.uri | http://dx.doi.org/10.1016/j.cap.2011.07.037 | en |
| dc.relation.uri | http://adsabs.harvard.edu/abs/2012CAP....12..401P | en |
| dc.rights | 2012 Elsevier B. V. | en |
| dc.subject | X-ray diffraction | en |
| dc.subject | Optical materials | en |
| dc.subject | Nonlinear optical | en |
| dc.subject | Optical limiting | en |
| dc.title | Optical limiting characteristics of Dichloridobis(1-ethyl-2, 6-dimethylpyridinium-4-olate-κO) zinc (II) | en |
| dc.type | Article | en |
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