Synthesis, optical nonlinearity and crystal structure of a novel mixed-chalcogen, thiolato-bridged complex [(5-C5H5)2Mo2(µ-S)(µ-Te)(µ-SPh)2
| dc.contributor.author | Mathur, P. | |
| dc.contributor.author | Ghose, Sanjukta | |
| dc.contributor.author | Trivedi, Rajiv | |
| dc.contributor.author | Gelinsky, Michael | |
| dc.contributor.author | Rombach, Michael | |
| dc.contributor.author | Philip, Reji | |
| dc.date.accessioned | 2012-06-19T03:46:49Z | |
| dc.date.available | 2012-06-19T03:46:49Z | |
| dc.date.issued | 2000 | |
| dc.description | Restricted Access. An open-access version is available at arXiv.org (one of the alternative locations) | en |
| dc.description.abstract | A novel dimolybdenum complex in which the metal atoms are bridged by two different chalcogens and two thiolato ligands has been synthesised and structurally characterised. This complex shows a large third-order optical nonlinearity as measured by degenerate four-wave mixing with picosecond excitation at 532 nm. A hyperpolarisability (γ) of 1.2×10−30 esu has been obtained. The structure of the complex was established by the single-crystal X-ray diffraction method. It consists of a Mo–Mo unit, which is bridged by one S, one Te and two (SPh) groups. Each Mo atom also has a (η5-C5H5) group attached to it. | en |
| dc.identifier.citation | Journal of Organometallic Chemistry, 2000, Vol.595, p140 | en |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | http://hdl.handle.net/2289/4727 | |
| dc.language.iso | en | en |
| dc.publisher | Elsevier B. V. | en |
| dc.relation.uri | http://arxiv.org/abs/ | en |
| dc.relation.uri | http://dx.doi.org/10.1016/S0022-328X(99)00648-8, | en |
| dc.rights | 2000 Elsevier B. V. | en |
| dc.title | Synthesis, optical nonlinearity and crystal structure of a novel mixed-chalcogen, thiolato-bridged complex [(5-C5H5)2Mo2(µ-S)(µ-Te)(µ-SPh)2 | en |
| dc.type | Article | en |