Synthesis and structure of 4-[(2,3,4,5,6-penta­fluoro­phen­­oxy)carbon­yl]phenyl 4-(tetra­dec­yl­oxy)benzoate

Abstract

In the title mol­ecule, C34H37F5O5, the dihedral angles between the central carbonyl­phenyl and adjacent perfluoro­phen­oxy and (tetra­dec­yloxy)benzoate rings are 74.19 (2) and 67.86 (2)°, respectively and the tetra­decyl chain adopts an extended conformation. In the crystal, the mol­ecules are linked by C—H⋯O and C—H⋯F hydrogen bonds, forming C(7) and C(10) chains, respectively, both running infinitely along [010]. The Hirshfeld surface analysis reveals that the major contributions to the two dimensional fingerprint plots are from H⋯H (49.4%), F⋯H/H⋯F (16.7%) and O⋯H/H⋯O (9.0%) contacts. An inter­molecular inter­action energy calculation shows that dispersion energy contributes the most to the consolidation of the structure.