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Molecular flexibility and orientational statistics in liquid crystals: Raman study of 7-CB and 8-OCB

dc.contributor.authorPrasad, S.N.
dc.contributor.authorVenugopalan, S.
dc.date.accessioned2006-05-16T11:15:48Z
dc.date.available2006-05-16T11:15:48Z
dc.date.issued1981-09-15
dc.description.abstractThe Raman depolarization ratios of the –C[equivalent]N vibrational band of 7-CB and 8-OCB have been measured in the aligned liquid crystal and isotropic phases. The temperature dependence of the absolute orientational order parameters <P2> and <P4> have been evaluated for the mesophases of both compounds. A comparison of their <P4> values in the nematic phase with those determined by Miyano for 5-CB suggests that molecular flexibility is an importnant factor that serves to lower <P4> well below the predictions of mean field theories.en
dc.format.extent271620 bytes
dc.format.mimetypeapplication/pdf
dc.identifier.citationJournal of Chemical Physics, 1981, Vol.75, p3033-3036en
dc.identifier.issn0021-9606
dc.identifier.urihttp://hdl.handle.net/2289/1267
dc.language.isoenen
dc.publisherThe American Institute of Physicsen
dc.relation.urihttp://link.aip.org/link/?jcp/75/3033en
dc.rights(1981) by the American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.en
dc.titleMolecular flexibility and orientational statistics in liquid crystals: Raman study of 7-CB and 8-OCBen
dc.typeArticleen

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