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Mesogenic β-diketones and metallonematogens

dc.contributor.authorGhode, Archana
dc.contributor.authorShivkumar, Uma
dc.contributor.authorSadashiva, B K
dc.date.accessioned2005-12-22T06:30:06Z
dc.date.available2005-12-22T06:30:06Z
dc.date.issued1994-06
dc.description.abstractSeveral new liquid-crystalline materials have been synthesized and their properties investigated. These belong to a series β-diketones containing different terminal substituents Mesophases of the smectic C, smectic A and nematic types have been observed in these β-diketones. Using these ligands many copper(I1) and palladium(I1) complexes have also been synthesized and their mesogenic behaviour characterized. Microscopic observations and diNeerentia1 scanning calorimetric measurements show that these chelates exhibit the nematic phase. The DSC data also indicate that the nematic phase of the ligands and complexes is associated with very low clearing transition enthalpies. All the metallonematogens reported are enantiotropic in nature.en
dc.format.extent602016 bytes
dc.format.mimetypeapplication/pdf
dc.identifier.citationBulletin of Materials Science, 1994, Vol. 17, p283-297.en
dc.identifier.issn0250-4707
dc.identifier.urihttp://hdl.handle.net/2289/784
dc.language.isoenen
dc.publisherIndian Academy of Sciences, Bangalore, India.en
dc.rightsIndian Academy of Sciences, Bangalore, India.en
dc.subjectMesogen: smectic;en
dc.subjectmetallonematogen: chelate;en
dc.subjectnematic: beta-diketone;en
dc.titleMesogenic β-diketones and metallonematogensen
dc.typeArticleen

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