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Calorimetric study of nonyloxybenzoyloxy-cyanoazobenzene (90BCAB)

dc.contributor.authorLeach, P
dc.contributor.authorDas, P
dc.contributor.authorGarland, C W
dc.contributor.authorShashidhar, R
dc.date.accessioned2007-05-19T09:38:56Z
dc.date.available2007-05-19T09:38:56Z
dc.date.issued1989-03
dc.descriptionRestricted Access.en
dc.description.abstractCalorimetric studies of 90BCAB have been made using DSC and high-resolution ac techniques. A small heat capacity peak associated with the smectic-Ad(SmAd)-reentrant nematic (Nr) second-order transition has been observed. Analysis in terms of the critical exponent agr suggests the possibility of Fisher renormalization at this SmAd-Nr transition. DSC measurements have shown the presence of two metastable crystal phases (denoted CrX and CrY) as well as the equilibrium CrK crystal phase. The latent heats for first-order transitions among these crystal phases and for the Nr-CrX and Nr-CrK melting/freezing transitions have been determined. The transition from Nt into the monotropic mon-olayer smectic-A phase was preempted in our experiments by Nr rarr CrX freezing.en
dc.format.extent313394 bytes
dc.format.mimetypeapplication/pdf
dc.identifier.citationMolecular Crystals and Liquid Crystals, 1989, Vol.168, p183-188en
dc.identifier.issn1058-725X
dc.identifier.urihttp://hdl.handle.net/2289/2347
dc.language.isoenen
dc.publisherGordon and Breach Science Publishers.en
dc.relation.urihttp://dx.doi.org/10.1080/00268948908045970en
dc.rights1989 OPA (Overseas Publishers Association) N.V.en
dc.titleCalorimetric study of nonyloxybenzoyloxy-cyanoazobenzene (90BCAB)en
dc.typeArticleen

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