Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/7611
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dc.contributor.authorMadhukar, S-
dc.contributor.authorRadhakrishnan, A.V.-
dc.contributor.authorMajhi, Amit Kumar-
dc.contributor.authorRaghunathan, V.A.-
dc.date.accessioned2021-01-11T08:35:53Z-
dc.date.available2021-01-11T08:35:53Z-
dc.date.issued2020-12-
dc.identifier.citationJournal of Chemical Physics, 2020, Vol.153, p224901en_US
dc.identifier.issn0021-9606-
dc.identifier.issn1089-7690 (Online)-
dc.identifier.urihttp://hdl.handle.net/2289/7611-
dc.descriptionRestricted Access.en_US
dc.description.abstractWe have studied the structure of cetyltrimethylammonium bromide–DNA complexes using small angle x-ray diffraction and elemental analysis. These complexes exhibit a two-dimensional hexagonal phase. The diffraction data have been analyzed using electron density models based on two different structures of these complexes proposed in the literature, which differ in the micelle to DNA stoichiometry. The structure with a 1:2 micelle–DNA stoichiometry is found to be more consistent with the diffraction data. Furthermore, this structure is also supported by the stoichiometry deduced from elemental analysis. Madelung energies of the two structures, calculated from the electrostatic interaction between their cylindrical constituents, give insight into their relative stability.en_US
dc.language.isoenen_US
dc.publisherAmerican Institute of Physicsen_US
dc.relation.urihttps://doi.org/10.1063/5.0033193en_US
dc.relation.urihttps://pubmed.ncbi.nlm.nih.gov/33317309/en_US
dc.rights2020 American Institute of Physicsen_US
dc.titleStructure and stoichiometry of CTAB–DNA complexesen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (SCM)

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