Please use this identifier to cite or link to this item: http://hdl.handle.net/2289/6235
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dc.contributor.authorDeepa, G.B.-
dc.contributor.authorRadhika, S.-
dc.contributor.authorSadashiva, B.K.-
dc.contributor.authorPratibha, R.-
dc.date.accessioned2015-05-13T11:56:57Z-
dc.date.available2015-05-13T11:56:57Z-
dc.date.issued2015-03-16-
dc.identifier.citationChemPhysChem, 2015, Vol. 16, p825-832en
dc.identifier.issn1439-4235-
dc.identifier.issn1439-7641(Online)-
dc.identifier.urihttp://hdl.handle.net/2289/6235-
dc.descriptionRestricted Access.en
dc.description.abstractDielectric spectroscopy is used to investigate the structure, molecular dynamics, and relaxation phenomena in electric-field-induced switchable dark conglomerate (DC) phases in a bent-core liquid crystal. The DC phases are obtained by applying a high-frequency ac electric field in the B1rev phase or by cooling under a dc or an ac field from the isotropic phase. Although the DC phases exhibit good electro-optic switching properties, the dielectric parameters are different from those observed in typical lamellar SmCP phases and similar to those obtained in a non-switchable DC phase. We therefore propose that the dielectric response and reduced intensity of the relaxation modes may be a general feature in DC phases and may owe its origin to the deformed layer structure in which certain molecular motions are impeded. Further, we find that in the field-induced DC phases derived from the isotropic phase, the dielectric modes are affected by chiral segregation promoted by the applied field.en
dc.language.isoenen
dc.publisherWiley-VCHen
dc.relation.urihttp://dx.doi.org/10.1002/cphc.201402714en
dc.rights2015 Wiley-VCHen
dc.titlePossible influence of layer deformation and Chiral segregation on dielectric modes in the dark conglomerate liquid crystalen
dc.typeArticleen
Appears in Collections:Research Papers (SCM)

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